QUOTE (Mark @ Oct 28 2005, 05:17 PM)

It seems your panel may not have been the ultimate in water sensitivity. oztang found his polarizer apparently completely dissolved when dunked? After what we have both seen with these tests, that is so hard to stomach, but we are waiting to hear back from him the details. Hopefully this is just an issue of dunking, and noticing damage as others have.

. Of course, keeping the water cool and using an actual rag technique (not a dunk) may have had very different results. At least for the first little while he says things went right

?
He wrote this in the water warning thread that Mikau set up. So hard to believe the grades could be that different?
Mark,
I replied to this this morning but the new engine was having problems and ate my post :angry: .
Here it is again:
I am surprised by Oztang's results of complete dissolution of the PVA, but not entirely worried by it. As you know, every solid has a solubility limit in water. At a given temperature and pressure, only so much material can dissolve in any given volume of water. Add more solid material, and it will refuse to dissolve. Take for example salt; there is only so much you can add to a cup of water before it reaches the solubility limit - adding more salt will merely result in the bottom of the cup having a layer of salt grains.
For PVA to dissolve fully, there needs to be a sufficient VOLUME of water in contact with the surface. This is why in our tests, direct immersion of the PVA in a droplet of water resulted in deterioration (large water volume relative to surface area of PVA). The effects of solubility are highly mitigated by using a ragging technique because there is only a thin skin of water (small volume) in contact with the surface of the PVA. Once the solubility limit is reached, no further PVA will dissolve. The PVA molecules in solution do not leach up into the rag to use the additional volume of water there.
How do I know this? In my panel, PVA has a strong odor when dissolved; after a few hours of direct immersion in a cup of water, the water has a pungent odor. Now when I sniffed the rags I used for the panel (okay, keep it clean now

), only the side exposed to the PVA had that odor. My conclusion is the PVA molecules in solution are confined to the thin skin of water between the rag and the PVA. The same principle would be in effect if the rag were applied on the a/g.
In both our tests, immersion resulted in damage. But ragging did not result in deterioration even after 2 days directly on the PVA. Oztang's sample did not start to deteriorate until the TAC layer was removed (resulting in a larger volume of water directly in contact with the PVA). Although I noted damage from my first 6 hour ragging test, I could not replicate that with subsequent tests on the same panel. My conclusion is that the damage I initally saw was pre-exisiting and not a result of ragging.
My polarizer also shredded when dunked in water. I am currently trying to replicate Ozstang's results, but I may have an insufficient volume of water in the cup. The water is taking on color and a pungent odor, but the polarizer is merely shredding. Do you know if
a ) Oztang used a large volume of water?
b ) Oztang used a small piece of polarizer?
It would be very interesting to see how his hydo-sensitive polarizer reacts to ragging.
PS: In searching the web, I am finding that Methylene Chloride attacks almost ALL polycarbonates. This is good news

for the stripping camp. I see stripping as a second alternative that can work if ragging fails.