QUOTE (GadgetSmith @ Oct 24 2005, 04:24 AM)

Isn't this "universal solvent" methylene chloride (paint stripper) ? As long as the specific brand of paint stripper doesn't have another active ingredient which would be harmful to PVA, a person using paint stripper should be fine, no ?
Nope. What I am looking for is the application and process of the rag technique, with a relatively PVA safe chemical, that will dissolve both water and oil based adhesives.
Paint stripper obliterates TAC. That is how it works. We can't design the rag technique around that fact.
Here is what I like about the rag technique:
1. No scraper, no squegee, no nothing.
2. If you have a panel that has zero bezel, you can still remove your anti-glare without praying to the gods of steady hand.
3. The anti-glare comes up, no questions asked, in one continues sheet. It just seems right.
So I need to rephrase (it was late when I wrote that

):
It is not the
water that impresses me about the rag technique, it is the application and process. It just seems right.
In the end, there are two failing points to water that were unclear, unproven, but speculated before the rag technique was written:
a. PVA is soluble in water.
GAH!. This bothered me immensly. It still bothers me immensely because I have no assurance that other panels have the same grade of PVA as mine. However, if they do have a similar grade, it turns out to not be as big an issue as I had thought. The rag technique has been shown to cause in-perceivable if any damage due to water solubility. That said, it is a problem. I personally don't want that burdening the process when it can so easily be resolved: A new solvent.
b. Water is not able to dissolve oil based PVA to TAC adhesives. Predicted. Now proven. This is a big one. I believe it to be the source of Mikau's woes (elaborated later).
QUOTE (GadgetSmith @ Oct 24 2005, 04:24 AM)

You said that you tested paint stripper and it also reacted to the PVA ? ... perhaps I missed that post... what specific paint stripper did you use, and what are it's active ingredients ? thanks... gonna try to find your post where to did this test...
SIMUL8TOR found that grain occurred after 24 hours:
QUOTE (SIMUL8R @ Oct 23 2005, 08:28 PM)

My guess is that this small deterioration was due to the chemical permeating thru the stress areas and started dissolving the adhesive between polar and plastic (the pattern of the deterioration appears to be speratic and diagonal). Otherwise the polar still maintained its structure, no frays or dissolving features noted.
That is the infamous grain. It is not a worry, though, because I have basically confirmed that it only occurs with stressed polarizers, and possibly only when solvent is applied to the back side. It also has occurred with every solvent I have tried
that could permeate through the TAC and PVA to TAC adhesive. What we really need to know is wether the crossed transmittance held up.I soaked an exposed section of PVA on it's backing in water for 4 days, and there was no visible damage but grain. Grain is the damage that Elken was describing as well.
The problem is that while they are holding up on first glance, according to Elken the samples are breaking down microscopically. This is experimentally confirmed by testing the crossed transmittance. Elken also put a piece under the microscope. I would say after the 4 day exposed PVA water dunk, the crossed transmittance looked to be somewhere around 1% instead of 0.001%. I still could not easily separate the PVA from it's backing. At 24 hours there seemed to be no change.
I would challenge that absolutely every solvent we've tried will cause damage to the PVA. We have yet to try a known PVA safe solvent other than mineral spirits (which also caused damage).
QUOTE (SonicWonder2000 @ Oct 24 2005, 07:48 AM)

Mark, I'm not so sure about this statement. Are you sure that the grain and degredation didn't appear due to the stress effects of peeling the polarizer?? According to elken's tests (goin on memory, might be wrong), his immersion-in-mineral-spririts sample did NOT show grain formation.
I immersed in mineral spirits. Everything held out much worse than even with water (exposed PVA 4 days). Under my tests it seems you need 3 conditions to produce grain:
1. A stressed polarizer. It must be stressed along the polarization axis. Thus, it depends to a small degree on what corner you started peeling the sample off the substrate earlier (with 45 degree polarizers).
2. The polarizer must then meet with a solvent
capable of dissolving the TAC to PVA adhesive. This is not just water. SIMUL8TOR has now seen it with stripper.
3. The solvent must come into contact with the side of the sample mentioned in 1. In this case, that is the back side of the polarizer.
If a polarizer is curled, the grain will appear on the outside of the roll.
QUOTE
One thing is CERTAIN, water does degrade PVA. PVA is soluble in water, and any application is going to be a balancing act in getting the correct exposure time without creating undue damage. There have been several members (elken and myself included) whose results bear this out. I think that it is fair to say that, at this point, even with the unknowns, the stripper method is a "safer" bet.
It really isn't that tricky. I would say by far the biggest problem with the rag technique is it's inability to dissolve all PVA to TAC glues. I encourage you to test the actual rag technique (not a dunk) and see just how well the PVA holds out. That said, as in my recent posts, I feel it more important than ever that we remove any possibility of PVA failure. This is not due to Mikau's experiences. Those have just made me more cautious. Here is what I believe happened with that panel:
It's PVA to TAC adhesive is not water soluble.
It's anti-glare
is permeable.
Water got all the way through the TAC and then was sealed out by the adhesive.
The anti-glare was pulled up. At times the adhesive chose to attached to the anti-glare, at times to the PVA.
This was a dry pull. Unfortunately something had to give eventually. Eventually the rear PVA adhesive was what chose to give. It was able to do this because both the front and rear adhesives were equally bonded.
I don't maintain with much confidence that this problem had anything to do with PVA degradation. But I want that
possibility gone just as much as everyone else. I am going to test a mineral spirit rag soak on my water soluble adhesive test panel. My hope is that the glue will release much quicker with Mineral Spirits than with water, as they may permeate the TAC quicker and dissolve the PVA quicker. I am still not sure about Mineral Spirits, though. I encourage others to test organic solvents, or oils with the rag technique (on test panels).
Again, dunking a section of polarizer, and treating it to the rag technique are very different. The dunking is a good indication of how damaging the chemical is to the PVA by exaggerating it's exposure. It is not an indication of what you're polarizer will look like given ragging. You
could remove your anti-glare with a know non-pva safe chemical and be laughing. Elken did it.
Mikau,
I just realized what may be getting us confused (aside from us not owning digital cameras):
The entire rectangle of plastic that the anti-glare peels from is called the laminate, or polarizer.
The section of your panel (almost the whole thing) that is made of glass is called the glass substrate.
The
layer of the laminate/polarizer that does the polarizing is called PVA film.
HTH,
Mark.