I think it would be best to start small first

If you are looking to get your home off the power grid you have a few really easy things to start doing. One minimize the amount of power you are using in the first place. There is a product called "green switch" that will turn off all the stuff left on that still uses power. things like VCRs stereos TV's etc that still draw power in standby mode. Make sure your attic and crawl space are properly insulated. Replace regular bulbs with the mercury vapor ones. Insulate the water heater and turn the temp to around 120deg to save energy.
And yes, there are ways to create more power then you use, which you can feed back to the grid and the power company pays YOU. Solar power is a good Idea, but it is not THAT cost effective. If you are in a windy area, you can get some regular wind turbines for around as much as you would pay for a couple solar panels. Not so high winds? Then you could put up some vertical shaft turbines that don't need as much wind speed to run. Those are a perfect project for the DIYer
Idaho National Laboratory has figured out how to do Infrared Solar panels at around 80% efficiency. They will work in cloudy weather and even at night from background IR energy. Once they get the rectifier design figured out they will be very rich. What you are thinking about may actually be very plausible since the design is VERY cheaply produced and could be "painted" on almost any surface.
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With the parabolic stuff, it becomes rather difficult because you need allow of surface area, not only on the ground, but with the reflective media. It would be a good DIY project, but if you are looking to power your home... Probably not the best.